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They also welcomed their second daughter Faith Margaret via a surrogate in December 2010.
The singer is believed to be worth an estimated million - a cool £57 million.
Her main man opted for a more casual look by sporting a plaid sports jacket and a button-up t-shirt.
The two were seen mingling with fellow country artist Kelsea Ballerini and Morgan Evans, as well as actresses Kimberly Williams-Paisley and Rita Wilson.
Nicole wore a bold and beautiful black dress with tulle, and had her blonde locks pulled back in a casual updo.
The solo artist has also been a coach on the Australian version of The Voice, as well as being a judge on American Idol.
Speaking about the track to Billboard, Keith explained: "It's all from a conversation my wife and I had early on in our relationship, that when things get tough, I need to hold her tighter and just try to take care of her.
"The song is about wanting to heal somebody, wanting to take care of somebody, wanting to protect somebody.
Keith reportedly received a million paycheck for his role as an American Idol judge in 2013.
While he has enjoyed great record and tour sales, with his album Be There going 4x Platinum.
When Urban was nominated for a 2018 People's Choice Award, Kidman told E! "Because, he's the loveliest, kindest man in the world.